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Analysis of Site Investigation Activities
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Location/MEDIUM to Be Sampled |
contaminaNT |
Justification |
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Surface soils on-site |
Lead |
24 of 57 surface soil samples greatly exceed the 1,400 mg/kg CUG for lead. Additional sampling and analysis should be conducted to better determine the location of and quantity of soil that will need to be removed and treated. |
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Surface soils in residential areas |
Lead |
To TOSC’s knowledge, no sampling and analysis of soils from residential properties has been accomplished. However, based upon the ENVIRON Draft EOC Report it appears that significant lead contamination of soils in the vicinity of residential properties has occurred. |
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Subsurface soils on-site (i.e., additional core samples) |
Lead |
Lead is present at significant depths in some soils. Additional sampling and analysis should be conducted to better determine the location of and quantity of soil that will need to be removed and treated. |
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Subsurface soils off-site in the parkway area (i.e., additional core samples) |
Lead |
Only 3 subsurface soil samples were analyzed for lead, so little is known about the depths at which lead is present. However, in 2 of these 3 samples that were analyzed, lead is present at depths of 1-2 ft. Sampling should be conducted to determine the depths to which lead is present. |
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Groundwater |
Lead |
In several locations lead is present at concentrations greater than 1,000 mg/kg at depths of up to 6-7 feet. As the groundwater table is reported to be at approximately 8 ft. below surface, the groundwater should be tested to ensure that it has not also become contaminated. |
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Surface and subsurface soils on-site (including, additional core samples) |
Diesel-related organics (DRO) |
The ENVIRON Draft EOC Report indicates that soil samples had concentrations of DROs that ranged from 11 to 26,000 mg/kg (some at depths of up to 6 feet). Additional sampling needs to be done to better characterize the type of contaminants and the extent to which contamination has occurred in both vertical and horizontal directions. |
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Surface and subsurface soils on-site (including, additional core samples) |
Gasoline-related organics (GRO) |
ENVIRON (1997) found that the concentration of GROs in on-site soils ranged from <0.5 to 5,600 mg/kg (some at depths of up to 5 feet). Additional sampling needs to be done to better characterize the type of contaminants and the extent to which contamination has occurred in both vertical and horizontal directions. |
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Debris pile on-site |
Asbestos and lead |
The debris pile contains 800 cubic yards of material that varies greatly in nature. Yet only four samples were taken. Also, TCLP lead concentrations were up to 3 mg/L and asbestos concentrations were up to 11%. Additional samples need to be taken to better characterize this material. Samples of each of the different types of materials should be obtained to evaluate the extent of contamination in these piles. |
Was the risk assessment adequate for the Dutch Boy site?
U.S. EPA used a streamlined risk evaluation to determine the on-site lead clean-up goal (CUG) under an occupational scenario. It is TOSC’s opinion that the risk assessment used is seriously flawed because no site-specific data have been used. In its risk assessment, U.S. EPA has not taken into account that residents of the two communities are likely to have been exposed to lead and may be further exposed in the future. The risk evaluation and, therefore, the proposed CUG are unacceptable. Below, we provide justification for that conclusion.
· The Edward White Elementary School property is approximately 1000 feet from the boundary of the Dutch Boy site and within 500 ft. of the area of significant contamination (that is, a lead concentration greater than 500 mg/kg). Residential properties are also located in the vicinity of the site. By assessing the site exclusively for future industrial use, the model ignores the site’s proximity to the community and thus seriously neglects the multiple exposure routes that exist. Further, children have historically accessed the site, and any risk assessment of the site needs to include the risk to children. EPA’s risk assessment, however, assumes that children will be prohibited from accessing the site and thus does not consider risk to children. That omission represents a serious flaw in the risk assessment. In a densely populated setting such as the site, banning an important segment of the population, namely children, also imposes a psychological burden upon the community. Unless the site is properly cleaned up, it will forever represent a legacy of contamination.
· The risk assessment model that was employed for this site ignores the risk posed by working parents bringing dust and soil home from the work place. Therefore, parents of young children are either deprived of potential employment opportunities or are constrained from traveling freely from the workplace to home. (For example, mothers with infants may rush to nurseries and homes during break time or right after work to nurse their babies without chance for a shower or change of clothes.) The risk assessment needs to account for workplace exposures and the potential for workplace-to-home transmission.
· A target blood lead level of 10 mg/dl was used in the risk assessment model. While TOSC recognizes that the U.S. EPA presently uses 10 mg/dl as the target blood lead concentration for children, we would like to note that neurodevelopmental effects are believed to occur in children whose blood lead level is 10 mg/dl. Since maternal blood lead diffuses readily to the fetus, maximum effort should be made to protect human health by ensuring a maternal blood lead concentration below 5 mg/dl.
· The baseline blood lead level is intended to represent the best estimate of the blood lead level in adults that have not been exposed to lead-contaminated soil from the site. A baseline blood lead level of 2.2 mg/dl was used in the model as an estimation of the background blood lead level in the adults living in the neighborhood. However, there is no evidence to indicate that the vast majority of adults living in the neighborhood have a blood lead level less than or equal to 2.2 mg/dl. In fact, based on conservative estimates, it is likely that, due to exposure to lead during childhood, many adults in this community may have grown up with blood lead levels of 15 mg/dl or greater. Therefore, the value of 2.2 mg/dl may not accurately represent the total body burden of lead that has been accumulated through residents’ lifetimes. As a result, the use of a 2.2 mg/dl blood lead level to determine the CUG may not provide sufficient protection from the deleterious effects of lead.
· The risk assessment lacks any calculation of the unavoidable background exposure to lead from other sources, such as drinking water, dust, soil, food and air, to which citizens may be exposed. Therefore, this assessment does not take into account that people on or near the site increase their lead exposures through such routine activities as drinking, eating and breathing. Site-specific data for lead concentrations in each medium should be gathered for inclusion in the risk assessment.
· The Leadville methodology uses an input lead absorption fraction of 0.12. That value was determined by using a relative absorption factor of 60% and an initial lead absorption fraction of 0.2. The risk assessment lacks justification for the 60% relative absorption factor, which may underestimate the risk from ingested lead. TOSC is requesting that justification of the value of 60% for the relative absorption factor be provided.
What is the risk to community residents due to non-occupational exposure?
To date, the risk to community residents due to non-occupational exposure has not been determined. Since the Leadville methodology that was used to determine the CUG for lead at on-site locations has been developed for occupational exposure, we concur with Lara Pullen’s conclusion that there is no justification to use that risk assessment model to determine clean-up criteria for off-site areas. TOSC, therefore, believes that it is imperative that the U.S. EPA determine risk-based clean-up goals for the non-industrial areas outside the site.
Do the current clean up criteria for the Dutch Boy site sufficiently protect human health?
It is our understanding that since the remediation of the site is to be accomplished under Section 106 (a) of CERCLA, 42 U.S.C Section 9606(a), all local, state and tribal Applicable, Relevant and Appropriate Requirements (ARARs) must be met. As such, under the State of Illinois regulations (35 Illinois Administrative Code Part 742), the site remediation (clean-up) criteria may be determined using the value determined from the methodology documented in the Tiered Approach to Corrective Action Objectives (TACO) report rather than that determined by U.S. EPA using the Leadville methodology (unless that value were more stringent than the ARARs). As such, TOSC continues to question why the TACO regulations are not an ARAR.
Most importantly, NL has not made a sufficient effort to ensure that the health and safety of those affected by the site are adequately protected. Requirements specified under the UAO have not been met. These include:
1. Identifying the vertical and horizontal extent of on-site soil contamination;
2. Determination of the background concentrations of lead in soils in the vicinity of the site; and
3. The determination as to whether lead is present at levels above background concentrations beyond the boundaries of the site.
In conclusion, what are the recommendations of TOSC?
In order to protect human health as required under the UAO, TOSC makes the following recommendations.
1. The U.S. EPA should revise the on-site lead clean-up goal (CUG) so that the health and safety of the population residing in the affected communities is protected, especially since residents may be exposed to lead from numerous other sources.
2. Additional soil sampling in residential areas should be conducted to determine the extent of contamination of various chemicals (see Table above).
3. Additional on-site sampling should be conducted to further and adequately characterize the extent of contamination (see Table above.) On-site cleanup goals (CUGs) should be developed for the other contaminants that were found on the site, including asbestos and petroleum-based organic chemicals.
4. The U.S. EPA should set off-site CUGs for lead and any other relevant chemical contaminants, taking into account all ARARs.
5. The health assessment proposed by the Agency for Toxic Substances and Disease Registry (ATSDR) should be conducted to ensure that intervention and protection measures will be implemented, in a timely manner, to address the health effects that may have resulted from a lifetime exposure to lead and possibly other chemicals present at the site. Additionally, the ATSDR should ensure that all proposed CUGs provide adequate protection of human health.
6. Based upon all these concerns, the U.S. EPA should enforce the UAO to the fullest extent of the law, so as to provide the necessary protection of human health and safety.
Appendix A: Dutch Boy Site History
The Dutch Boy site was used by NL Industries, Inc. (NL) from 1906 through mid-1977 for the manufacture of lead and lead-based paints. The manufacture of lead-based paints was continued through 1980 by ARTRA Group, Inc. (ARTRA). The manufacturing of lead-based paints at the site ceased in 1980 when ARTRA sold its paint division to Sherwin-Williams Company and donated the property to Goodwill.
Demolition of the steel and brick building on the site began in 1983 and was terminated in 1986 when the Illinois Department of Public Health (IDPH), the Illinois Environmental Protection Agency (IEPA) and the City of Chicago found that lead and asbestos dust created by the demolition activities posed an imminent danger to the community. In 1986, the IDPH notified the IEPA that five cases of lead poisoning that had resulted could be traced to lead at the site. The source of lead poisoning was attributed to solid lead particles, which had become airborne during demolition activities. Asbestos was also detected inside the building structures.
In June 1986, IEPA initiated an immediate removal at the site. Among the materials removed were surficial solids, both suspected and known to contain lead and/or asbestos; liquids, solids and sludges from aboveground and underground storage; and process/ production equipment and debris. IEPA also sampled and analyzed the soil for lead contamination. The results indicated significant contamination, with approximately 140 cubic yards of soil containing greater than 1% lead. Several site investigations were conducted subsequent to the removal effort. All of these indicated on-site contamination with lead. A study by Toxcon Engineering Company, Inc. in June 1987, also indicated off-site contamination.
During the period of time from 1986 until 1995, the site was apparently visited by children and homeless persons. Based upon the site assessments that were conducted, Ecology and Environment, Inc. (E&E), a contractor to the U.S. Environmental Protection Agency (U.S. EPA), concluded that the site should be secured and an extent of contamination study should be conducted to determine the extent of lead-contamination at the site. On March 26, 1996, a unilateral Administrative Order (UAO) was issued to NL by William E. Muno, Director, Superfund Division, U.S.EPA, Region 5. It became effective 10 business days after its issuance. Among the requirements of the order was an extent of contamination study. In summer of 1996, the site was secured by the installation of a six-foot fence around the periphery of the site.
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