CMSCourier Newsletter

Volume I Issue 5 ...... June 1993

Inside This Issue

1993-94 Research Excellence Fund
SEM Elects New President
Water-Environment Effects on Anomalous Absorption Behavior in Grpahite/Epoxy Composite
October 93 Conferences and Seminars
Calendar of Events

1993-94 Research Excellence Fund

The Research Excellence Fund (REF) is a state of michigan program designed to focus resources on a limited number of specific basic and applied research proposals of outstanding quality which will contribute to economic development and job creation within the state of Michigan. The REF monies are intended to provide support to start new and novel research efforts, encourage new multi-investigator, interdisciplinary efforts and attract external funding in support of faculty research which will contribute to the long term economic vitality of the state of michigan as stated in the REF objectives. Each project undertaken by an institution must be in a field where quality and institutional committment are already strong. Composite materials and processing has been designated as a major thrust area at MSU.

In response to the 1993/94 Research Excellence fund for proposals in the composite materials and processing area, fifty-one (51) proposals with a total requested funding amount of $2,062,800 were received for the funding period July 1, 1993 to June 30, 1994. The amount of funding available was approximately $952,000. The following proposals were selected for funding:

THRUST AREA 1. REDUCED COST COMPOSITE CONSTITUENTS (FIBER OR MATRIX)

Microsorting Mixed Thermoplastic Waste Streams Using Hydrocyclone Classifiers - $34,000-Renewed

Project Investigator: Dr. Eric Grulke, Chemical Engineering

Co-Invetigator: Dr. Charles A. Petty, Chemical Engineering

Co-Investigator: Dr. Susan E. Selke, Packaging

Recycling of Plastics and Paper in Concrete Composites to Control Shrinkage Cracking and Brittle Failure Modes - $45,000-Renewed

Project Investigator: Dr. Parviz Soroushian, Civil & Envirnmental Engineering

Functionalized Polylactides for Recyclable, Low Cost Composites - $35,000-New

Project Investigator: Dr. Ramani Narayan, Chemical Engineering

THRUST AREA 2. NEW HIGH PERFORMANCE COMPOSITE MATERIALS

Disorder and Mechanical Failure: Application to Ceramic Composites - $23,000-Renewed

Project Investigator: Dr. P. M. Duxbury, Physics and Astronomy

Co-Investigator: Dr. Ostoja-Starzweski, Materials Science & Mechanics

A New Technique for Making Continuous Fiber Metal Matrix Composites - $15,000-Renewed

Project Investigator: Dr. Thomas R. Bieler, Materials Science & Mechanics

Thermal and Mechanical Fatigue of Ceramic Composties as a Function of Volume Fraction Reinforcement - $34,000-Renewed

Project Investigator: Dr. Eldon Case, Materials Science & Mechanics

Co-Investigator: Dr. Melissa J. Crimp, Materials Science & Mechanics

Co-Investigator: Dr. Gary Cloud, Materials Science & Mechanics

Modification of Metal-Matrix Composite Reinforcements for Control of Interface Reactions by Ion Enhanced Deposition - $20,000-Renewed

Project Investigator: Dr. David S. Grummon, Materials Science & Mechanics

The Effect of Interface on the Local and Global Response of Composite Materials - $16,000-Renewed

Project Investigator: Dr. Iwona Jasiuk, Materials Science & Mechanics

Chemistry of Protective Coatings for Fiber-Reinforced Composites - $17,000-Renewed

Project Investigator: Dr. Jeffrey Ledford, Chemistry

Fabrication of Textured High Temperature Superconductor/Silver Layered Composites by Laser Melting - $21,000-Renewed

Project Investigator: Dr. Kali Mukherjee, Materials Science & Mechanics

Optimization of Metal-Ceramic Bonding to Enhance Mechanical Properties of Ceramic Matrix

Project Investigator: Dr. K. N. Subramanian, Materials Science & Mechanics

In-situ of Fatigue Crack Initiation and Propogation in Metal Matrix Composites - $22,297-New

Project Investigator: Dr. Martin A. Crimp, Materials Science & Mechanics

High-Energy Ion Irradation of Single-Crystal Sapphire Fibers for Improved Strength Retention in High Temperature Metal-Matrix Composites - $22,500-New

Project Investigator:Dr. David Grummon, Materials Science & Mechanics

Clay-Polymer Nanocomposites - $44,000-New

Jointly funded with Center for Fundamental Materials Research.

Project Investigator: Dr. Thomas J. Pinnavaia, Chemistry

Co-Investigator: Dr. P. M. Duxbury, Physics and Astronomy

Co-Investigator: Dr. Jack Giacin, Packaging

Co-Investigator: Dr. Rueben J. Hernandez, Packaging

Co-Investigator: Dr. Lawrence T. Drzal, Chemical Engineering

Metallic-Glass Ribbon Reinforced Polymer Matrix Composites - $20,000-New

Project Investigator: Dr. K. N. Subramanian, Materials Science & Mechanics

THRUST AREA 3. NEW AND/OR NOVEL COMPOSITE PROCESSING AND FABRICATION METHODS

Processing of Silicon Nitride/Silicon Carbide Whisker Composites - $27,340-New

Project Investigator: Dr. Melissa J. Crimp, Materials Science & Mechanics

Fundamentals of Microwave Heating and Microwave Pultrusion - $50,000-Renewed

Project Investigator: Dr. Martin C. Hawley, Chemical Engineering

Co-Investigator: Dr. Jess Asmussen, Electrical Engineering

Reactive Processing of Chopped Fiber Composites With Phenolic Resins: Injection Molding - $35,000-Renewed

Project Investigator: Dr. Jayaraman, Chemical Engineering

Co-Investigator: Dr. C. A. Petty, Chemical Engineering

Laser Machining and Joining of Metal-Matrix Composites - $26,326-Renewed

Project Investigator: Dr. Kali Mukherjee, Materials Science & Mechanics

Simultaneous Radical and Cationic Polymerizations of Novel Polymer Composites - $20,000-Renewed

Project Investigator: Dr. Alec Scranton, Chemical Engineering

High Speed Videography of Fiber Transport and Deposition onto a Preform Screen - $30,000-New

Project Investigator: Dr. Charles A. Petty, Chemical Engineering

Co-Investigator: Dr. Jayaraman, Chemical Engineering

Co-Investigator: Dr. John F. Foss, Mechanical Engineering

THRUST AREA 4. PERFORMANCE AND DESIGN MODELLING

A Micromechanics-Based Failure Criterion for Progressive Failure Analysis of Composites - $16,259-Renewed

Project Investigator: Dr. Ronald C. Averill, Materials Science & Mechanics

Diamond Film Characterization by Nanoindentor - $12,500-Renewed

Project Investigator: Dr. Eldon Case, Materials Science & Mechanics

Co-Investigator: Dr. Ronald C. Averill, Materials Science & Mechanics

Measurement of Anisotropic Electromagnetic Properties of Composite Materials - $21,000-Renewed

Project Investigator: Dr. Kun-Mu Chen, Electrical Engineering

A Novel Fastening System for Composites - $21,000-Renewed

Project Investigator: Dr. Gary Cloud, Materials Science & Mechanics

Non-Linear Random Vibration of Structural Systems Made of Composite Materials - $20,000-Renewed

Project Investigator: Dr. R. Harichandran, Civil & Environmental Engineering

An Optimum Laminate Theory for Composite Crashworthiness Analysis- $23,000-Renewed

Project Investigator: Dr. Dahsin Liu, Materials Science & Mechanics

Geometric Imperfection in Composite Design and Manufacturing - $15,000-Renewed

Project Investigator: Dr. Dahsin Liu, Materials Science & Mechanics

Instability Studies in Nonlinearly Elastic Composite Materials - $21,000-Renewed

Project Investigator: Dr. Thomas J. Pence, Materials Science & Mechanics

Multidimensional Thermal Properties of High Temperature Composites using CVD Diamond as Both Heater and Temperature Sensor - $20,000-New

Project Investigator: Dr. James Beck, Mechanical Engineering

Co-Investigator: Dr. Mohammad Aslam, Electrical Engineering

New Approaches to Composite Materials - $36,000-New

Jointly funded with Center for Fundamental Materials Research

Project Investigator: Dr. Michael F. Thorpe, Physics and Astronomy

Co-Investigator: Dr. Iwona Jasiuk, Materials Science & Mechanics

Performance and Design Testing of Elastomeric Composite Tubes - $20,897-New>

Project Investigator: Dr. Clark Radcliffe, Mechanical Engineering

Co-Investigator: Dr. Charles MacCluer, Mathematics

Reinforcement of Concrete Structures with Fiber Reinforced Plastic Tendons - $19,551-New

Project Investigator: Dr. Parviz Soroushian, Civil & Environmental Engineering

THRUST AREA 5. ADVANCED DETECTION AND CONTROL METHODS FOR COMPOSITE MANUFACTURING

Nondestructive Evaluation of Composite Materials and Structures by Ultrasonics - $20,000-Renewed

Project Investigator: Dr. Bong Ho, Electrical Engineering

Co-Investigator: Dr. Ronald H. Zapp, Electrical Engineering

Fiber Orientation Distributions in Thermoplastic Injection Molding - $30,000-Renewed

Project Investigator: Dr. John McGrath, Mechanical Engineering

Electronic Holography and Shearography for Inspection of Composite Vessels - $21,000-New

Project Investigator: Dr. Gary Cloud, Materials Science & Mechanics

In-Situ Cure Monitoring for Composites Processing Using Fiber Optic Fluorescence Sensors - $20,000-New

Jointly funded with Center for Fundamental Materials Research

Project Investigator: Dr. Alec Scranton, Chemical Engineering

Co-Investigator: Dr. Gary Blanchard, Chemistry

THRUST AREA 6. ENVIRONMENTAL EFFECTS OF COMPOSITE PERFORMANCE

Physical Aging Effects on Service Environmental Performance of Polymeric Matrix Composites - $26,000-New

Project Investigator: Dr. Andre Lee, Materials Science & Mechanics

Co- Investigator: Dr. Roger Morgan, Chemical Engineering

Partitioning of Moisture in Resin Matrix Composites: Effects on Microfracture and Deformation Behavior - $15,000-New

Project Investigator: Dr. James Lucas, Materials Science & Mechanics

SEM Elects New President

Dr. Gary Cloud, professor of Materials Science and Mechanics and Biomechanics, has been appointed as the 1993-94 President of the Society of Mechanical Engineers (SEM). SEM is an international professional society dedicated to advancing scientific knowledge in the field of manufacturing engineering and management. Founded in 1932, SEM has more than 75,000 members in 68 countries and sponsors over 325 senior chapters and 220 student chapters worldwide.

Cloud has outlined the objectives of his presidency in two general goals and a number of specific tasks. The first of his general goals is to "increase the technical relevance of SEM and its activities to a broader segment of the technological community, including technicians, manufacturers and engineers, as well as our important core of academicians." His second objective is to encourage the society to "develop a vision as to what the field of experimental mechanics will be evolving into over the next several years.

Specific tasks which Cloud hopes to accomplish include reformatting of conferences, realignment of the Technical Divisions, creation of strategic planning task forces, a revitalization of the Education Committee, and the formation of a new program to raise capital.

Water-Environment Effects on Anomalous Absorption Behavior in Grpahite/Epoxy Composite!

Jiming Zhou (Graduate Student, Materials Science & Mechanics),
James P. Lucas (Associate Professor, Materials Science and Mechanics)

To gain acceptance for application in marine or high moisture environments, resin matrix composties must be thoroughly characterized. The water-environment effects on moisture absorption characterisitcs of unidirectional T300/934 graphite/epoxy composite material were investigated by the measurement and analysis of weight change, hygrothermal induced expansion, the observation of crack formation, and surface mass loss. Non-Fickian diffusion behavior of moisture was observed in resin matrix composite materials by previous investigations. However, up to now, the rational for this anomalous behavior has been presented in an ambiguous manner.

Specimens were immersed in distilled water at 45, 60, 75, and 90 Degrees C for more than 9000 hours. The material exhibited both Fickian and Non-Fickian diffusion behavior. Absorption data showed that the onset of Non-Fickian behavior ocurred sooner at higher exposure temperatures.

Anomalous absorption behavior in the composite occurs as a result of chemical modification and physical damage. Scanning electron microscopy and dimensional measurements revealed clear evidence of surface peeling and resin dissolution of the specimen. A crack/mass loss model can be used to give an explantation of the behavior of Graphite/Epoxy composite during the water absorption process. At near room temperature, there is no surface dissolution or physical damage of the material and hence weight gain behavior is Fickian as indicated by the 45 degree C exposure temperature. With increasing exposure temperature, cracks, voids, surface peeling, and dissolution occur. Cracks can retain water which contributes to enhanced absorption behavior higher than the theoretical Fickian diffusion curve. Surface peeling and dissolution contribute to a reduction in the specimen weight. Consequently, the weight change profile data falls below the theoretical Fickian diffusion curve. The basis for interpreting the crack/mass loss model stems from the fact that two competing effects persist. If only cracking occurs in the material, the experimental absorption data profile will be higher than Fickian curve due to water retention at the crack tips. Conversely, if surface dissolution and peeling occur during exposure, the experimental data profile will be lower than Fickian curve resulting from mass loss. The absorption data profile represents the combined effects of cracking and mass loss.

October Conferences and Seminars

In order to increase communications between the Composite Materials and Structures Center and its various members, we would like to inform you of upcoming conferences and seminars pertaining to your research areas. Here is a list of October seminars and conferences which might be of interest. Brochures on these conferences are available at the Composite Center. Please contact Margie Gray at (517)353-5466 for any requests.

Society of Plastics Engineers - Practical Applications for Melt Rheology in Polymer Processing Workshop.

Location: Cherry Hill, NJ

Dates: 10/4-5/93

Society of Plastics Engineers - Alloy, Blends and Modified Polymers (to provide "State-of-the-Art" information on Polymer Aloys and Blends).

Location: Akron, OH

Dates: 10/5-6/93

Society of Manufacturing Engineers (SME) - Fundamentals of Injection Molding (One-day course will cover, basics of injection molds and related accessories; overview of the design considerations for injection molded plastic parts; understand the trouble-shooting process; the importance of quick mold change systems).

Location: Chicago, IL

Dates: 10/12/93

Society of Plastic Engineers Decorating Division - Regional Educational Technical Conference - (Distribute new information on plastics decorating, while also addressing the associated environmental impact).

Location: Nashville, TN

Dates: 10/12-13/93

Society of Manufacturing Engineers (SME) - Designing Plastic Injection Molds (Two-day clinic, overview of various CAD/CAE; gate location and type selection; the effects material type has on mold design; ways to solve tooling problems).

Location: Chicago, IL

Dates: 10/13-14/93

The Minerals, Metals & Materials Society and ASM International - Materials Week '93

Location: Pittsburgh, PA

Dates: 10/17-21/93

Center for Professional Advancement - Statistical Process Control: Basic and Advanced Topics. - A two/three/five day Practical Course with Hands-On Computer Case Studies.

Location: East Brunswick, NJ

Dates: 10/18-22/93

American Society for Composites - 8th Technical Conference of Composite Materials - (All types of composites such as polymeric composites, metal matrix composites, etc...).

Location: Cleveland, OH

Dates: 10/19-21/93

Society for American Manufacturers and Processing Engineers - 14th International European Conference/Expo.

Location: Birmingham, England

Dates: 10/19-21/93

American Society of Civil Engineers 1993 Annual Convention and Exposition - CExpo and Transpo '93.

Location: Dallas, TX

Dates: 10/24-28/93

Society of Plastics Engineers - Chicago, IL Seminars - (Extrusion of polymers; injection mold tooling technology; injection molding-advanced concepts and analyses; die design principles for extrusion of polymers; extrusion principles and practices; thermoforming technology for industrial applications).

Location: Chicago, IL

Dates: 10/25-27/93

Center for Professional Advancement - Planning and Analyzing Industrial Experiments - R & D, Pilot Plant - Three day Partial Course with Case Studies and PC Workshops.

Location: East Brunswick, NJ

Dates: 10/25-27/93

Society for the Advancement of Material and Process Engineering. 25th International SAMPE Technical Conference. (Advanced Materials Expanding the Horizons).

Location: Philadelphia, PA

Dates: 10/26-28/93

American Institute for Chemical Engineers - Center for Chemical Process Safety - Process Safety Management Training Course (Design and Evaluation of Process Safety Management Systems).

Location: St. Louis, MO

Dates: 10/27-29/93

also

Location: New York, NY

Dates: 12/7-9/93

Calendar of Events!

American Institute of Chemical Engineers - Safety Analysis and Risk Assessment for Chemical Process Inustry Practitioners - COURSE 1: Hazards Evealuation: Qualitative Methods

St. Louis, MO

Atlanta, GA

11/1-5/93

4/11-15/94

U.S. Department of Energy - Tenth International Symposium on Alcohol Fuels (examine scientific and technical advances for the use and production of alcohol fuels).

Colorado Springs, CO

11/7-10/93

3/31/93

7/15/93

The 9th Annual ASM/ESD Advanced Composite Confernece and Exposition

Dearborn, MI

11/8-11/93

4/23/93

5/6/93

Society of Manufacturing Engineers - Autofact '93 Conference and Expostion - (Manage your transition to integrated manufacturing with practical applications & techniques).

Chicago, IL

11/7-11/93

American Institute of Chemical Engineers - Safety Analysis and Risk Assessment for Chemical Process Industry Practitioners - COURSE 2: Hazards Evaluation: Quantitative Methods.

St. Louis, MO

Atlanta, GA

11/15-19/93

4/25-29/94

American Institute of Chemical Engineers - Safety Analysis and Risk Assessment for Cehmical Process Industry Practitioners - COURSE 3: Consequence Assessment & Mitigation

St. Louis, MO

Atlanta, GA

11/29-12/2/93

5/2-5/94

Materials Research Society - Technical Symposia, Short Courses, Equipment Exhibit and Table-Top Display (Each symposium will provide a forum for scientist and engineers to exchange information and ideas at the forefront of materials research).

Boston, MA

11/29-12/3/93

6/20/93

Society of Plastics Engineers - Continuous Compounding in the 90's RETEC (A three day technical conference for new and evolving theories and applications for value added compounding).

Somerset, NJ

11/30-12/2/93

Composite Materials and Structures Center
College of Engineering
Michigan State University
East Lansing, MI 48824-1326

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